It will work, at least for tax years 2015 onwards.  Windows 10 was released in 2015 and it was explicit that PS for TY2015 supports Windows 10.

https://accountants-community.intuit.com/articles/1867544-system-requirements-for-2015-proseries-pro...

Theoretically, legacy programs may also be compatible with Windows 10.  See this article for more details: https://support.microsoft.com/en-us/help/15078/windows-10-make-older-apps-or-programs-compatible